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Rookie 'Event' Mission lines. Look for an "Event" Agent in the station(s) in these systems.
You get free items and free frigate class ships from them.

Be careful of the military event missions.

Business Mission Lines:
Amarr: Conoban
Caldari: Jouvulen
Gallente: Trossere
Minmatar: Embod

Industrial MIssion Lines:
Amarr: Pasha
Caldari: Todaki
Gallente: Clellinon
Minmatar: Malukker

Military MIssion Lines:
Amarr: Deepari
Caldari: Uitra
Gallente: Couster
Minmatar: Hadaugago

you should run the training missions for each group at least once for the implants and skillbooks.